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Research progress of palladium-based catalysts for oxidation of low concentration methane

Received Date:2022-12-06 Revised Date:2023-01-12 Accepted Date:2023-04-24

DOI:10.20078/j.eep.20230122

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    Abstract:Methane (CH_4) is an important greenhouse gas that is 25 times that its CO_2 equivalent. There is low concentration (0.0... Open+
    Abstract:

    Methane (CH_4) is an important greenhouse gas that is 25 times that its CO_2 equivalent. There is low concentration (0.05% ~0.5%) CH_4 leakage in marine natural gas engine exhaust. It is difficult to capture and utilize low concentration CH_4 because of its stable chemical structure and high ignition temperature. Catalytic oxidation is the main method to remove low concentration CH_4 from tail gas. The noble metal palladium (Pd) is the best catalytic material for the complete oxidation of low concentration CH_4. In this paper, the main research progress of Pd-based catalysts is reviewed for their low-temperature activity, reliability and development cost. Firstly, the effects of Pd particle size and valence distribution, Pd dispersion state, type of support and strong metal-support interaction (SMSI) on methane oxidation activity are clarified; then, the mechanism of methane oxidation on the surface of Pd-based catalysts is summarized; in addition, the deactivation mechanisms of Pd-based catalysts, such as high temperature sintering, water poisoning and sulfur poisoning, are described in detail; finally, the main challenges and the future development of Pd-based catalysts for the complete oxidation of low concentration methane are summarized, and the strategies for improving the performance of Pd-based catalysts are proposed.

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    Authors:

    • ZHAO Xuteng1
    • HOU Jin2
    • WANG Yinan1
    • GUI Yu 1
    • ZHANG Yiran1
    • LI Ke2
    • CHEN Ting1
    • LIN He1,*

    Units

    • 1. School of Mechanical Engineering, Shanghai Jiao Tong University
    • 2. Shanghai Marine Diesel Engine Research Institute

    Keywords

    • Natural gas engine
    • Palladiumbased catalyst
    • Low concentration methane
    • Catalytic oxidation

    Citation

    ZHAO Xuteng, HOU Jin, WANG Yinan, et al. Research progress of palladium-based catalysts for oxidation of low concentration methane[J]. Energy Environmental Protection, 2023, 37(2): 106-116.

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