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Advances in catalyst metals and supports for lignin hydrogenation

Received Date:2024-08-01 Revised Date:2024-08-22

DOI:10.20078/j.eep.20240809

Abstract:Developing technology for the utilization of lignin resources to obtain high-value aromatic chemicals will not only incr... Open+
Abstract:

Developing technology for the utilization of lignin resources to obtain high-value aromatic chemicals will not only increase the economic value of lignin but also help achieve the "double carbon" goal. Considerable research elorts have been directed toward investigating lignin hydrogenation. Based on the different types of hydrogen donors, lignin hydrogenation can be divided into exogenous hydrogen (including molecular hydrogen, alcohol solvents, or fommic acid) and endogenous hydrogen supply (lignin self-transfer hydrogenolysis). Lignin hydrogenation olfers notable advantages, such as high product yields and relatively simple product compositions. However, harsh reaction conditions have prompted the development of efficient hydrogenation catalysts. The focus of research is on regulating the active metal and support centers of hydrogenation catalysts to improve the activity. Through extensive studies of numerous lignin hydrogenation catalysts, advances in lignin hydrogenation depolymerization have been summarized. The influence of metal oxygen affinity, along with the different catalytic effects of various sizes of metal on the product distribution of lignin depolymerization through exogenous hydrogen supply and self-transfer hydrogenolysis, is analyzed. Additionally, the impacts of acidity, surface funetional groups, and porous and defective structures of supports on catalytic performanee are elucidated. Finally, the prospective outlook on the future of lignin resource utilization is presented.

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Authors:

  • GAO Jie1,2,3,4
  • ZHANG Yitian1,2,3,4
  • LUO Gang1,2,3,4
  • CAO Yang5,*
  • ZHANG Shicheng1,2,3,4,*

Units

  • 1. Department of Environmental Science and Engineering, Fudan University
  • 2. Shanghai Technical Service Platform for Pollution Control and Resource Utilization of Organic Wastes
  • 3. Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention LAP3
  • 4. Shanghai Institute of Pollution Control and Ecological Security
  • 5. Department of Civil and Environmental Engineering, The Hong Kong Polytechnic University

Keywords

  • Lignin
  • Hydrodepolymerization
  • Oxygen afflinity of active metal
  • Size effect of active metal
  • Support acidity
  • Support structure

Citation

GAO Jie, ZHANG Yitian, LUO Gang, CAO Yang, ZHANG Shicheng. Advances in catalyst metals and supports for lignin hydrogenation[J/OL]. Energy Environmental Protection: 1-13[2024-09-03]. https://doi.org/10.20078/j.eep.20240809.

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