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Research advances in anti-water/sulfur/ammonium nitrate poisoning of ultra-low temperature denitrification catalysts

Received Date:2024-04-20 Revised Date:2024-05-25

DOI:10.20078/j.eep.20240605

Abstract:The strict control of nitrogen oxides (NO_x) is an urgent task for improving China's air quality, and selective cata... Open+
Abstract:

The strict control of nitrogen oxides (NO_x) is an urgent task for improving China's air quality, and selective catalytic reduction (SCR) with ammonia represents the dominant method for treatment of NO_x exhaust from industries. As the focus of SCR denitrification shifts from thermal power plants to non-electric industries such as steel and cement kilns, the overall working temperature of SCR showsan obvious shift to lower temperatures. Specifically, the flue gas temperature for denitrification is usually below 150 ℃ when a desulfurization treatment is pre-installed. Under these circumstances, achieving long-term and stable operation of denitrification catalysts becomes a pivotal challenge for the application of SCR technology. A decrease in reaction temperature can exacerbate not only water and sulfur poisoning but also induce new deactivation problems due to ammonium nitrate deposition. Therefore, this comprehensive review presents the research progress on the poisoning resistance of SCR catalysts under ultra-low temperatures. The paper starts with introducing the changes in denitrification performance caused by temperature reduction. After brielly deseribing catalyst deactivation and its characteristics, the main focus is on the developed poisoning resistance strategies against water/sulfur/ammonium nitrate. These strategies are discussed from the perspectives of denitrification catalyst structure modulation, combined purification process selection, and regulation of the reaction atmosphere. Furthermore, we introduce the research progress on anti-poisoning strategies and provide a discussion of anti-poisoning mechanism. Finally, considering the practical application requirements, a prospect for the future development direction of poisoning resistance studies in ultra-low temperature denitrification is presented.


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Authors:

  • AN Dongqi1
  • CHENG Qianni2
  • SONG Wang1
  • ZHAO Yonggang3
  • SUN Jingfang4,*
  • TANG Changjin5,*
  • DONG Lin1,2

Units

  • 1.Jiangsu Key Laboratory of Vehicle Emissions Control, School of Chemistry and Chemical Engineering,Nanjing University
  • 2. School of Environment, Naning University
  • 3. Jiangsu Ningtian Environmental Technology Co., Ltd.a
  • 4. Center of Modern Analysis, Nanjing University
  • 5. jiangsu Province Engineering Research Center of Environmental Risk Prevention and Emergency Response Technology, School of Environment, Nanjing Normal University

Keywords

  • SCR
  • Ultra low temperature denitrification
  • Denitrification catalysts
  • Poisoning resistanceAmmonium nitrate

Funded projects

江苏省杰出青年基金资助项目(BK20230007); 国家自然科学基金青年科学基金资助项目(22202100);国家自然科学基金面上资助项目(22276097)

Citation

AN Dongqi, CHENG Qianni, SONG Wang, ZHAO Yonggang, SUN Jingfang, TANG Changjin, DONG Lin. Research advances in anti-water/sulfur/ammonium nitrate poisoning of ultra-low temperature denitrification catalysts[J/OL]. Energy Environmental Protection: 1-14[2024-06-20]. https://doi.org/10.20078/j.eep.20240605.

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